金属—二乙基二硫代氨基甲酸螯合物的气相色谱研究——（Ⅱ）螯合物的气—液色谱行为

金属—二乙基二硫代氨基甲酸螯合物的气相色谱研究——（Ⅱ）螯合物的气—液色谱行为 GAS CHROMATOGRAPHIC STUDY OF METAL-DIETHYLDITHIOCARBAMATE CHELATES （Ⅱ）The gas-liquid chromatographic behavior of chelates 胡继明 first-author 刘良斌 刘锦春 程介克 夏幽兰 龙清凤 本文系统地研究了十四种金属—二乙基二硫代氨基甲酸螯合物在三种固定液相（SE—30,OV—101,OV—17）上的气液色谱行为。探讨了螯合物的保留值与柱温、固定液平均极性、元素的原子序数和离子半径的关系。在恒温和程序升温下,对一系列二组份和多组份混合物成功地进行了分离。 The paper has systematically investigated the gas-liquid chromatographic behavior of fourteen metal-diethyldithiocarbamate chelates on the three stationary liquids（SE—30, OV—101, OV—17）. The relation between the retention data of the metal chelates and the column temperature, the mean polarity of the stationary liquid, the atomic number and the ion radious of metal have been discussed in detail. The successful separation a serious of two or multi-component mixtures have been achieved under the both isothermal or temperature programming. 1983-02-01 2021-04-01 2