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[1]甘复兴,邹津耘,姚录安.黄铜阳极溶解分反应动力学研究[J].武汉大学学报(自然科学版),1983(01):91-102.
Gan Fuxing Zou Jinyun and Yao Luan. KINETICS STUDY OF PARTIAL ANODIC DISSOLUTION REACTIONS OF BRASS[J]. 1983,(1):91-102.
<正> 合金阳极过程是一个复杂的电极过程,它包含若干组分之间相互平行而又相互影响的阳极分反应。近年来,随着电化学实验技术的发展,人们开始进行合金阳极过程各分反应速度的测量和动力学性质的探讨[1-7],这对于深入揭示合金阳极过程的动力学规律,具有十分重要的意义。测量合金阳极过程分反应速度即分电流的方法,目前采用的已有溶液分析、示踪原子、旋转圆盘-圆环电极等。因旋转盘-环电极遵循理想的对流扩散规律,可严格控制传质动力学条件,且响应时间比较快、灵敏度较高,是研究合金阳极过程分反应动力学比较优越的手段。原则上讲,测定了分电流,就可绘出分反应的极化曲线,计算分反应动力学参数,推测分反应的机埋。但由于实际过程比较复杂,目前对合金阳极过程分反应动力学作定量处理的文献还很少。
Kinetics behaviors of partial anodic dissolutlon reactions of α-brass (Cu30Zn) were investigated in 0.5N NaCl—0.01N HCl deaerated solution with rotating ring-disc electrode. The partial anodic current densities of zinc and copper(i,zn, and i,cu,) of brass were measured respectively. For the partial reactions and the total reaction of Cu30Zn, two distinct linear regions in the φ-lg i relations were all found with slopes corresponding respectively to 60 and 130mV. The characteristic of the partial polarization curve of copper shows that the reaction rate is mass-diffusion-controlled for i,Cu,<,lmA/cm,2, and activation-controlled for i,Cu,>,lmA/cm,2,. In case of uniform-dissolution of an alloy in a solution containing no M,n+, a expression for partial anodic reaction polarization curve of constituent M of an alloy was derived: where According to the expression the kinetics parameters of the partial anodic reaction of copper for Cu3OZn were calculated as following: β=0.45, i,Cu,0,*,=2.7×10,-3,A/cm, K=1.1×10,-3,cm/sec.
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