Wade规则在稠合型多面体硼烷中的应用

Wade规则在稠合型多面体硼烷中的应用 Application of the Wade Rule in Joined-type Polyhedral Boranes 杨雪梅 YANG Xue-mei 1 2 first-author 胡培植 HU Pei-zhi 1 2 武汉大学化学与分子科学学院 武汉大学化学与分子科学学院 College of Chemistry and Molecular Science, Wuhan University College of Chemistry and Molecular Science, Wuhan University 武汉大学化学与分子科学学院,湖北,武汉,430072 武汉大学化学与分子科学学院,湖北,武汉,430072 讨论了 Wade规则经数学转换后在稠合型多面体硼烷中的应用 .推广后的 Wade规则可以计算稠合型多面体硼烷的价成键电子对数 BEP;根据稠合方式也可以计算稠合型多面体硼烷的骨架成键电子对数 SEP;还可以推断某些稠合型硼烷的结构 . We have discussed the application of the Wade rule which is transformed by mathematics ways in joined-type polyhedral boranes. The Wade rule transformed can calculate the number of bonding electron pairs, which is the same as those from Tang Aoqing’s topological formula. If the joined way is known, the rule can calculate the number of skeleton bonding electron pairs. We can also infer the structure of some joined-type polyhedral boranes on basic of them. Wade规则 稠合型多面体硼烷 价成键电子对数 骨架成键电子对数 Wade rule joined-type polyhedral boranes number of bonding electron pairs number of skeleton bonding electron pairs O641 2001-06-01 2021-04-01 6