均分散球形TiO₂制备中的若干影响因素

均分散球形TiO 2 制备中的若干影响因素 Key Factors on Preparing Superfine Dispersed Spherical TiO 2 Particles by Hydrolysis 昝菱 ZAN Ling 1 first-author 刘忠士 LIU Zhong-shi 1 钟家柽 ZHONG Jia-cheng 1 武汉大学化学与分子科学学院,湖北,武汉,430072 武汉大学化学与分子科学学院,湖北,武汉,430072 College of Chemistry and Molecule Sciences, Wuhan University College of Chemistry and Molecule Sciences, Wuhan University 介绍了用盐水解制备超细均分散球形 Ti O2 的方法 ,详细讨论了浓度、酸度、阴离子、陈化时间、锻烧温度等因素对制备超细球形 Ti O2 的影响 ,用透射电镜和粒度分析仪分析了 Ti O2 的粒度和形貌 ,得到了均匀分散性好 ,金红石型结构 ,2μm左右的球形 Ti O2 . The superfine dispersed spherical particles of TiO 2 was prepared by hydrolysis method. The morphology, the size, the crystalline of the partical, were measured by X-ray diffraction and TEM. The effect of anions, pH, concentration of reactant, aging on the formation of spherical particle was studied systematically. The formation domain of spherical particle was given. It is shown that the change of reactant concentration and pH cause the variety of particle shape. The lower concentration, the lower pH values （higher acidty）, the easier the formation of spherical particles. When a trace sulfate ion was added to the solution that is in the spherical domain, The spherical particles cann’t be gotten. Only the smaller, non-spherical particles can be found. The aging at room temperature was effective to the dispersal. On aging the particles tends to become smaller and well dispersal. The impact of different calcining temperature on the size, morphology and crystalline was investigated. The higher the calcining temperature, the higher the rutile content, and the more dispersion. In this experiment, rutile, spherical and well dispersed TiO 2 particles about 2μm were obtained. 二氧化钛 分散球形粒子 水解法 制备 TiO2 spherical dispersal particles hydrolysis preparation TB383;TF123 国家教委九·五攻关资助项目 !（96 -5 5 4-0 3-0 1） 2001-02-01 2021-04-01 2