四苯基卟啉的微波合成

四苯基卟啉的微波合成 The Microwave Synthesis of Tetraphenyl-Porphyrin 陈年友 CHEN Nian-you 1 2 first-author 赵胜芳 ZHAO Sheng-fang 1 2 廖学红 LIAO Xue-hong 1 2 舒峰 SHU Feng 1 2 黄冈师范学院化学系 黄冈师范学院化学系 Department of Chemistry,Huanggang Normal University Department of Chemistry,Huanggang Normal University 黄冈师范学院化学系,湖北,黄冈,438000 黄冈师范学院化学系,湖北,黄冈,438000 采用微波辐射的方法合成四苯基卟啉,分析和讨论了溶剂、催化剂、微波辐射时间及微波输出功率等因素对合成产率的影响.结果表明:在溶剂为硝基苯、催化剂为氯乙酸、微波功率为195W、反应时间为6min的条件下合成四苯基卟啉,最高产率可达35.94%,优于文献结果. Tetraphenyl-porphyrin was synthesized with microwave radiant method. The influence of solvent, catalyst, reactional period, reactional concentration and microwave radiant power in TPP synthesis on the yield of product has been analyzed and discussed. The experimental results show that the yield of tetraphenylporphyin may reach as high 35.94% under the condition of the uses of nitrobenzene as solvent, chloroacetic acid as catalyst and 195 W microwave intermittent radiation for 6 min. 四苯基卟啉 微波合成 反应条件 tetraphenyl-porphyrin microwave synthesis reactional condition O625 湖北省教育厅重点科研项目基金资助（1999A083,2002A04002） 2004-02-01 2021-04-01 2