1＇－O－（苯甲酰）－2＇，3＇，4＇，6＇－四－O－乙酰－β－D－吡喃葡萄糖类化合物合成

1＇－O－（苯甲酰）－2＇，3＇，4＇，6＇－四－O－乙酰－β－D－吡喃葡萄糖类化合物合成 SYNTHESES OF 1’-O-BENZOYL-2’3’,4’ 6’-TETRA-O-ACETYL-β-D-GLUCOSYL ESTERS 刘惠英 1 first-author 杨振海 1 傅莎莉 1 李宝睿 1 武汉大学化学系 武汉大学化学系 Department of Chemistry, Wuhan University Department of Chemistry, Wuhan University 本研究以苯甲酸—类化合物为母体，在羧基上引入葡萄糖，形成本甲酸四乙酰葡萄糖酯，合成出１０个苯甲酸类四乙酰葡萄糖酯．对这１０个化合物进行了元素分析、ＩＲ测定，对其中部分化合物作了１ＨＮＭＲ的ＵＶ测定，确证了化合物的结构．对所选化合物５作了质谱测定，化合物１进行了热分解的研究． O-benzoyl-2’, 3’, 4’, 6’-tetra-O-acety1-β-D-glucosy1 esters have been prepared bymeans of the phase-transfer catalytic method. All ten compounds are discriminated and discussed in thepresent paper. Their chemical structures have been comfirmed by IR,EA and some compounds run byUV and 1HNMR. Compound 5 has been measured using mass spectra and compound 1 identified usingDTA/TG/GC combined technique through heat decomposition. 芳香羧酸 相转移催化方法 葡萄糖酯 arylcarboxylic acid phase-transfer catulytic method glucosyl esters Q532.3 1994-02-01 2021-04-01 2