具有亚乙基二硫醚基团的网状聚合物冠醚

具有亚乙基二硫醚基团的网状聚合物冠醚 NETWORK POLYMERIC CROWN ETHER WITH ETHYLENE BISTHIOETHER GROUPS 陈远荫 1 first-author 孟令芝 1 殷以华 1 武汉大学化学系 武汉大学化学系 Department of Chemistry, Wuhan University Department of Chemistry, Wuhan University 具有亚乙基二硫醚基团的网状聚合物冠醚陈远荫，孟令芝，殷以华（武汉大学化学系，武汉，４３００７２）关键词聚合物冠醚，亚铂配合物，硅氢加成催化剂中图法分类号Ｏ６３２·３１通过非冠醚单体的聚合直接合成聚合物冠醚，在一定程度上解决了冠醚化合物价格昂贵、难以回... The ring-opening copolyrnerization of β（β-ethylthioethylthio） ethyl glycidyl ether and diethylene glycol bisglycidyl ether has been investigated. It was found that this reaction could be catalyzed by Bull and the obtained polymer could be co-ordinated with potassium chloroplatinite. The platinum complex is a new kind of hydrosilylation catalyst,and can catalyze the hydrosilylation of olefins with triethoxysilane efficiently. 聚合物冠醚 亚铂配合物 硅氢加成催化剂 polymeric crown ether platinous complex hydrosilylation catalyst O632.32 1995-06-01 2021-04-01 6