氨基J酸新合成方法的研究及其在有机合成中的应用（I）

氨基J酸新合成方法的研究及其在有机合成中的应用（I） STUDY ON NEW SYNTHETIC METHOD OF AMINO J ACID AND ITS APPLICATION 张治民 Zhang Zhimin 1 first-author 邱孝群 Qiu Xiaoqun 1 粱淑彩 Liang Shucai 1 谢亮 Sheng Zheng 1 武汉大学化学学院 武汉大学化学学院 College of Chemistry, Wuhan University College of Chemistry, Wuhan University 以吐氏酸为原料，用发烟硫酸作磺化剂合成了中间体氨基Ｊ酸，对反应的关键条件发烟硫酸的浓度、二磺化和三磺化的温度以及水解温度进行了优化，提出了一条切实可行的合成路线，并对它作为有机合成中间体的应用作了概括． Amino J acid（2 amino 5,7 naphthalenedisulfonic acid）,a valuable intermediate in organic synthesis, was synthesized from tobias（2 amino 1 naphthalenesulfonic acid） and oleum by a new procedure in good yield. The conditions of the reaction were studied and a practicable synthesis route was proposed. The applications of amino J acid were also described. 吐氏酸 氨基J酸 磺化 中间体 tobias amino J acid sulfonation intermediate O621.3;O625.6 1998-02-01 2021-04-01 2