四苯骈卟啉锌纯化和脱锌的研究

四苯骈卟啉锌纯化和脱锌的研究 Improvement About Purifying Method of Tetrabenzporphyrinate Zinc（Ⅱ） and Studies on Demetalization of Tetrabenzporphyrinate Zinc（Ⅱ） 周晓海 ZHOU Xiao\|hai 1 first-author 方义东 FANG Yi\|dong 1 邓立志 DENG Li\|zhi 1 卢卫兵 LU Wei\|bing 1 武汉大学化学与环境科学学院,武汉,430072 武汉大学化学与环境科学学院,武汉,430072 College of Chemistry and Environment Science, Wuhan University, Wuhan 430072,China) \ \ College of Chemistry and Environment Science, Wuhan University, Wuhan 430072,China) \ \ 通过系统研究,改进了四苯骈卟啉锌的纯化和脱锌的方法,发现用浓硫酸脱锌时绿色物质的生成与温度有关. 纯化方法经改进,产率和纯度均有所提高. The synthesis of zinc（Ⅱ） tetrabenzporphyrin was reviewed and the purifying method of product was improved. Some questions about demetalization, including the cause that green substance present and factors that effect purifying, were explored. By improving, the green substance no longer yield.\; 四苯骈卟啉锌 四苯骈卟啉 纯化 脱锌 tetrabenzporphyrin zinc（Ⅱ） tetrabenzporphyrin purify demetalization of tetrabenzporphyrinate Zinc（Ⅱ） O626.2 教育部博士点专项基金!（9448606）;国家自然科学基金!(29871024;29773033) 1999-06-01 2021-04-01 6