Extensive experimental and theoretical data in literature are analyzed for solid Au at high temperatures up to 5 000 K.It is demonstrated in this paper that the P-V-T relation below the melting temperature 1 336.4 K can be described by the universal equation of state(UEOS) for solids proposed by Vinet et al
while for temperatures higher than the melting point
we proposed a new equation of state(EOS) for solid Au
taking the melting curve as the reference state
for the description of the high pressure and high temperature behavior.The fitting of the existing literature data shows the full applicability of the proposed equation.
关键词
固体状态方程压强-体积-温度关系普适状态方程熔化曲线预熔化状态
Keywords
equation of state for solidspressure-volume-temperature relation(P-V-T)universal equation of state for solidsthe melting curvepremelting state