基于MOFs和酚醛泡沫的多孔碳泡沫电容性能
A Porous Carbon Foam Derived from MOFs and Phenolic Foam and Its Capacitive Performance
- 武汉大学学报（理学版）
- 作者机构：
1.武汉理工大学 化学化工与生命科学学院，湖北 武汉 430070
- 作者简介：
李 曦， 女， 教授，现从事电化学研究。 E-mail：chemlixi@whut.edu.cn
- 基金信息：国家自然科学基金(51273155);国家级大学生创新创业训练项目(20181049715023;201710497056);武汉理工大学自主创新研究基金本科生项目(2018-HS-B1-041)
DOI：10.14188/j.1671-8836.2019.04.010
中图分类号： O 69;TM 53纸质出版日期：2019-08-24，
收稿日期：2018-10-30，
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引用本文
李曦,王晨,蔡旻堃, 等.基于MOFs和酚醛泡沫的多孔碳泡沫电容性能[J].武汉大学学报（理学版）,2019,65(4):383-389.
LI Xi,WANG Chen,CAI Minkun,et al.A Porous Carbon Foam Derived from MOFs and Phenolic Foam and Its Capacitive Performance [J].J Wuhan Univ （Nat Sci Ed）,2019,65(4):383-389.
李曦,王晨,蔡旻堃, 等.基于MOFs和酚醛泡沫的多孔碳泡沫电容性能[J].武汉大学学报（理学版）,2019,65(4):383-389. DOI：10.14188/j.1671-8836.2019.04.010
LI Xi,WANG Chen,CAI Minkun,et al.A Porous Carbon Foam Derived from MOFs and Phenolic Foam and Its Capacitive Performance [J].J Wuhan Univ （Nat Sci Ed）,2019,65(4):383-389. DOI：10.14188/j.1671-8836.2019.04.010(Ch).
摘要
以酚醛泡沫为碳源，金属有机框架材料Cu-MOF-199为掺杂剂，经过高温碳化制备了一种电容性能优良、循环稳定性强的多孔碳泡沫。采用热重-差示扫描量热法（TG-DSC）、X射线衍射（XRD）、X射线光电子能谱（XPS）、扫描电镜（SEM）、氮气吸脱附测试等技术对材料的结构和形貌进行分析，采用循环伏安法（CV）、恒电流充放电（GCD）及电化学阻抗谱（EIS）等方法对材料的电化学性能与循环性能进行测试。结果表明，一定量Cu-MOF-199的引入可明显提升多孔碳泡沫的电容性能，在1 A·g,-1,时可达169 F·g,-1,，20 A·g,-1,时仍高达123 F·g,-1,，2 500次循环（1 A·g,-1,）后仍有97%的电容量。
Abstract
With the phenolic foam as the carbon source and a metal-organic frameworks Cu-MOF-199 as the dopant, a porous carbon foam with the high capacitive performance and cyclability stability was prepared by the high-temperature carbonization. Thermal analysis-differential scanning calorimetry (TG-DSC), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and N,2, adsorption-desorption were employed to characterize the composition, structure and morphology of the prepared material. The electrochemical properties of the material were tested by cyclic voltammetry (CV), galvanostatic charge-discharge method (GCD) and electrochemical impedance spectroscopy (EIS). The results demonstrate that the incorporation of Cu-MOF-199 can conspicuously promote the capacitive performance. The specific capacitance could reach 169 F·g,-1, at 1 A·g,-1, and 123 F·g,-1, at 20 A·g,-1, respectively. Meanwhile the carbon foam maintains 97% retention after 2 500-cycle GCD test at 1 A·g,-1,.
关键词
超级电容器碳泡沫酚醛树脂金属有机框架（MOF）
Keywords
supercapacitorcarbon foamphenolic resinmetal-organic framework（MOF）
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