1.华中农业大学 理学院,湖北 武汉 430070
2.华中农业大学 资源与环境学院,湖北 武汉 430070
3.江汉大学 光电材料与技术学院,湖北 武汉 430056
杜英侠,女,博士生,现从事生物质衍生碳材料研究。E-mail:d8012198@163.com
E-mail: zhanggeng@mail.hzau.edu.cn
caofeifei@mail.hzau.edu.cn
收稿:2021-12-15,
纸质出版:2022-04-24
移动端阅览
杜英侠,刘瑞,鲁望婷, 等.生物质衍生碳材料电催化裂解水研究进展[J].武汉大学学报(理学版),2022,68(2):123-130.
DU Yingxia,LIU Rui,LU Wangting,et al.Research Progress of Biomass-Derived Carbon Materials as Catalysts for Electrochemical Water Splitting [J].J Wuhan Univ (Nat Sci Ed),2022,68(2):123-130. DOI:10.14188/j.1671-8836.2021.0344(Ch).
杜英侠,刘瑞,鲁望婷, 等.生物质衍生碳材料电催化裂解水研究进展[J].武汉大学学报(理学版),2022,68(2):123-130. DOI:10.14188/j.1671-8836.2021.0344
DU Yingxia,LIU Rui,LU Wangting,et al.Research Progress of Biomass-Derived Carbon Materials as Catalysts for Electrochemical Water Splitting [J].J Wuhan Univ (Nat Sci Ed),2022,68(2):123-130. DOI:10.14188/j.1671-8836.2021.0344(Ch). DOI:
生物质衍生碳材料具有独特的形貌、高的比表面积、分级多孔的结构和丰富的杂原子,在电催化领域具有广阔的应用前景。本文系统总结了生物质衍生碳材料的制备方法及相关机制,探讨了制备条件对碳材料结构和性能的影响,综述了生物质衍生碳材料在电催化裂解水(析氧反应和析氢反应)中的应用,并提出了其在电催化领域未来的研究方向。
Biomass-derived carbon materials inherit the characteristics of biomass itself
including unique natural morphology
high specific surface area
hierarchical porous structure and rich heteroatoms
which makes them have a promising application prospect in the field of electrocatalysis. The paper summarizes the preparation methods of biomass-derived carbon materials and their corresponding mechanisms
discusses the effect of preparation conditions on the structure and performance of carbon materials
then reviews the application of biomass-derived carbon materials as the electrocatalysts for water splitting (oxygen evolution reaction and hydrogen evolution reaction)
and finally suggests the future research direction of biomass-derived carbon materials in the field of electrocatalysis.
YU Z Y , DUAN Y , FENG X Y , et al . Clean and affordable hydrogen fuel from alkaline water splitting: past, recent progress, and future prospects [J]. Advanced Materials , 2021 , 33 ( 31 ): e2007100 . DOI: 10.1002/adma.202007100 http://dx.doi.org/10.1002/adma.202007100 .
LI Y , WANG H H , PRIEST C , et al . Advanced electro-catalysis for energy and environmental sustainability via water and nitrogen reactions [J]. Advanced Materials , 2021 , 33 ( 6 ): e2000381 . DOI: 10.1002/adma.202000381 http://dx.doi.org/10.1002/adma.202000381 .
CHANDRASEKARAN S , MA D T , GE Y Q , et al . Electronic structure engineering on two-dimensional (2D) electrocatalytic materials for oxygen reduction, oxygen evolution, and hydrogen evolution reactions [J]. Nano Energy , 2020 , 77 : 105080 . DOI: 10.1016/j.nanoen.2020.105080 http://dx.doi.org/10.1016/j.nanoen.2020.105080 .
ZHANG G , FENG Y S , LU W T , et al . Enhanced catalysis of electrochemical overall water splitting in alkaline media by Fe doping in Ni 3 S 2 nanosheet arrays [J]. ACS Catalysis , 2018 , 8 ( 6 ): 5431 - 5441 . DOI: 10.1021/acscatal.8b00413 http://dx.doi.org/10.1021/acscatal.8b00413 .
CHEN N , DU Y X , ZHANG G , et al . Amorphous nickel sulfoselenide for efficient electrochemical urea-assisted hydrogen production in alkaline media [J]. Nano Energy , 2021 , 81 : 105605 . DOI: 10.1016/j.nanoen.2020.105605 http://dx.doi.org/10.1016/j.nanoen.2020.105605 .
YANG D , CAO L Y , FENG L L , et al . Formation of hierarchical Ni 3 S 2 nanohorn arrays driven by in - situ generation of VS 4 nanocrystals for boosting alkaline water splitting [J]. Applied Catalysis B: Environmental , 2019 , 257 : 117911 . DOI: 10.1016/j.apcatb.2019.117911 http://dx.doi.org/10.1016/j.apcatb.2019.117911 .
WANG T , WANG P , ZANG W , et al . Nanoframes of Co 3 O 4 -Mo 2 N heterointerfaces enable high-performance bifunc tionality toward both electrocatalytic HER and OER [J]. Advanced Functional Materials , 2021 , 2107382 . DOI: 10.1002/adfm.202107382 http://dx.doi.org/10.1002/adfm.202107382 .
ZHOU P , TAO L , TAO S S , et al . Construction of nickel-based dual heterointerfaces towards accelerated alkaline hydrogen evolution via boosting multi-step elementary reaction [J]. Advanced Functional Materials , 2021 , 31 ( 46 ): 2104827 . DOI: 10.1002/adfm.202104827 http://dx.doi.org/10.1002/adfm.202104827 .
ZHU J W , GUO Y , LIU F , et al . Regulative electronic states around ruthenium/ruthenium disulphide heterointerfaces for efficient water splitting in acidic media [J]. Angewandte Chemie (International Edition in English) , 2021 , 60 ( 22 ): 12328 - 12334 . DOI: 10.1002/anie.202101539 http://dx.doi.org/10.1002/anie.202101539 .
LI Q , LIU Y P , WANG Y , et al . Review of the application of biomass-derived porous carbon in lithium-sulfur batteries [J]. Ionics , 2020 , 26 ( 10 ): 4765 - 4781 . DOI: 10.1007/s11581-020-03694-3 http://dx.doi.org/10.1007/s11581-020-03694-3 .
牛海涛, 生物质能源技术应用研究 [J]. 生物化工 , 2017 , 3 ( 4 ): 84 - 86 . DOI: 10.3917/rn.174.0084 http://dx.doi.org/10.3917/rn.174.0084 .
NIU H T . Application research of biomass energy technology [J]. Biological Chemical Engineering , 2017 , 3 ( 4 ): 84 - 86 (Ch) . DOI: 10.3917/rn.174.0084 http://dx.doi.org/10.3917/rn.174.0084 .
KIM H , KIM H , DING Z , et al . Recent progress in electrode materials for sodium-ion batteries [J]. Advanced Energy Materials , 2016 , 6 ( 19 ): 1600943 . DOI: 10.1002/aenm.201600943 http://dx.doi.org/10.1002/aenm.201600943 .
CHEN Q , TAN X F , LIU Y G , et al . Biomass-derived porous graphitic carbon materials for energy and environmental applications [J]. Journal of Materials Chemistry A , 2020 , 8 ( 12 ): 5773 - 5881 . DOI: 10.1039/c9ta11618d http://dx.doi.org/10.1039/c9ta11618d .
XING C Y , XUE Y R , HUANG B L , et al . Fluorographdiyne: A metal-free catalyst for applications in water reduction and oxidation [J]. Angewandte Chemie (International Edition in English) , 2019 , 58 ( 39 ): 13897 - 13903 . DOI: 10.1002/anie.201905729 http://dx.doi.org/10.1002/anie.201905729 .
SENTHIL C , LEE C W . Biomass-derived biochar materials as sustainable energy sources for electrochemical energy storage devices [J]. Renewable and Sustainable Energy Reviews , 2021 , 137 : 110464 . DOI: 10.1016/j.rser.2020.110464 http://dx.doi.org/10.1016/j.rser.2020.110464 .
SEKHON S S , LEE J , PARK J S . Biomass-derived bifunctional electrocatalysts for oxygen reduction and evolution reaction: A review [J]. Journal of Energy Chemistry , 2022 , 65 : 149 - 172 . DOI: 10.1016/j.jechem.2021.05.052 http://dx.doi.org/10.1016/j.jechem.2021.05.052 .
WANG J , NIE P , DING B , et al . Biomass derived carbon for energy storage devices [J]. Journal of Materials Chemistry A , 2017 , 5 ( 6 ): 2411 - 2428 . DOI: 10.1039/c6ta08742f http://dx.doi.org/10.1039/c6ta08742f .
CHEN Y Z , ZOU K Y , DAI X , et al . Polysulfide filter and dendrite inhibitor: Highly graphitized wood framework inhibits polysulfide shuttle and lithium dendrites in Li-S batteries [J]. Advanced Functional Materials , 2021 , 31 ( 31 ): 2102458 . DOI: 10.1002/adfm.202102458 http://dx.doi.org/10.1002/adfm.202102458 .
QU W H , XU Y Y , LU A H , et al . Converting biowaste corncob residue into high value-added porous carbon for supercapacitor electrodes [J]. Bioresource Technology , 2015 , 189 : 285 - 291 . DOI: 10.1016/j.biortech.2015.04.005 http://dx.doi.org/10.1016/j.biortech.2015.04.005 .
LU H , ZHAO X S . Biomass-derived carbon electrode materials for supercapacitors [J]. Sustainable Energy Fuels , 2017 , 1 ( 6 ): 1265 - 1281 . DOI: 10.1039/C7SE00099E http://dx.doi.org/10.1039/C7SE00099E .
LI Y , LI D W , RAO Y , et al . Superior CO 2 , CH 4 , and H 2 uptakes over ultrahigh-surface-area carbon spheres prepared from sustainable biomass-derived char by CO 2 activation [J]. Carbon , 2016 , 105 : 454 - 462 . DOI: 10.1016/j.carbon.2016.04.036 http://dx.doi.org/10.1016/j.carbon.2016.04.036 .
YU M , HAN Y Y , LI J , et al . CO 2 -activated porous carbon derived from cattail biomass for removal of malachite green dye and application as supercapacitors [J]. Chemical Engineering Journal , 2017 , 317 : 493 - 502 . DOI: 10.1016/j.cej.2017.02.105 http://dx.doi.org/10.1016/j.cej.2017.02.105 .
MATSAGAR B M , YANG R X , DUTTA S , et al . Recent progress in the development of biomass-derived nitrogen-doped porous carbon [J]. Journal of Materials Chemistry A , 2021 , 9 ( 7 ): 3703 - 3728 . DOI: 10.1039/d0ta09706c http://dx.doi.org/10.1039/d0ta09706c .
WANG P , ZHANG G , LI M Y , et al . Porous carbon for high-energy density symmetrical supercapacitor and lithium-ion hybrid electrochemical capacitors [J]. Chemical Engineering Journal , 2019 , 375 : 122020 . DOI: 10.1016/j.cej.2019.122020 http://dx.doi.org/10.1016/j.cej.2019.122020 .
BENÍTEZ A , AMARO-GAHETE J , CHIEN Y C , et al . Recent advances in lithium-sulfur batteries using biomass-derived carbons as sulfur host [J]. Renewable and Sustainable Energy Reviews , 2022 , 154 : 111783 . DOI: 10.1016/j.rser.2021.111783 http://dx.doi.org/10.1016/j.rser.2021.111783 .
CHEN Z H , DU X L , HE J B , et al . Porous coconut shell carbon offering high retention and deep lithiation of sulfur for lithium-sulfur batteries [J]. ACS Applied Materials & Interfaces , 2017 , 9 ( 39 ): 33855 - 33862 . DOI: 10.1021/acsami.7b09310 http://dx.doi.org/10.1021/acsami.7b09310 .
SINGH G , KIM I Y , LAKHI K S , et al . Heteroatom functionalized activated porous biocarbons and their excellent performance for CO 2 capture at high pressure [J]. Journal of Materials Chemistry A , 2017 , 5 ( 40 ): 21196 - 21204 . DOI: 10.1039/c7ta07186h http://dx.doi.org/10.1039/c7ta07186h .
WANG C J , WU D P , WANG H J , et al . A green and scalable route to yield porous carbon sheets from biomass for supercapacitors with high capacity [J]. Journal of Materials Chemistry A , 2018 , 6 ( 3 ): 1244 - 1254 . DOI: 10.1039/c7ta07579k http://dx.doi.org/10.1039/c7ta07579k .
PENG X W , ZHANG L , CHEN Z X , et al . Hierarchically porous carbon plates derived from wood as bifunctional ORR/OER electrodes [J]. Advanced Materials , 2019 , 31 ( 16 ): e1900341 . DOI: 10.1002/adma.201900341 http://dx.doi.org/10.1002/adma.201900341 .
WANG P , YE H , YIN Y X , et al . Fungi-enabled synthesis of ultrahigh-surface-area porous carbon [J]. Advanced Materials , 2019 , 31 ( 4 ): 1805134 . DOI: 10.1002/adma.201805134 http://dx.doi.org/10.1002/adma.201805134 .
KIM J , PARK J , LEE J , et al . Biomass-derived P, N self-doped hard carbon as bifunctional oxygen electrocatalyst and anode material for seawater batteries [J]. Advanced Functional Materials , 2021 , 31 ( 22 ): 2010882 . DOI: 10.1002/adfm.202010882 http://dx.doi.org/10.1002/adfm.202010882 .
PANG H P , SUN P P , GONG H Y , et al . Wood-derived bimetallic and heteroatomic hierarchically porous carbon aerogel for rechargeable flow Zn-air batteries [J]. ACS Applied Materials & Interfaces , 2021 , 13 ( 33 ): 39458 - 39469 . DOI: 10.1021/acsami.1c10925 http://dx.doi.org/10.1021/acsami.1c10925 .
WU H , GENG J , GE H T , et al . Egg-derived mesoporous carbon microspheres as bifunctional oxygen evolution and oxygen reduction electrocatalysts [J]. Advanced Energy Materials , 2016 , 6 ( 20 ): 1600794 . DOI: 10.1002/aenm.201600794 http://dx.doi.org/10.1002/aenm.201600794 .
SORDELLO F , PELLEGRINO F , PROZZI M , et al . Controlled periodic illumination enhances hydrogen production by over 50% on Pt/TiO 2 [J]. ACS Catalysis , 2021 , 11 ( 11 ): 6484 - 6488 . DOI: 10.1021/acscatal.1c01734 http://dx.doi.org/10.1021/acscatal.1c01734 .
ZHU G Y , MA L B , LÜ H L , et al . Pine needle-derived microporous nitrogen-doped carbon frameworks exhibit high performances in electrocatalytic hydrogen evolution reaction and supercapacitors [J]. Nanoscale , 2017 , 9 ( 3 ): 1237 - 1243 . DOI : 10.1039/c6nr08139h http://dx.doi.org/10.1039/c6nr08139h .
SARAVANAN K R A , PRABU N , SASIDHARAN M , et al . Nitrogen-self doped activated carbon nanosheets derived from peanut shells for enhanced hydrogen evolution reaction [J]. Applied Surface Science , 2019 , 489 : 725 - 733 . DOI: 10.1016/j.apsusc.2019.06.040 http://dx.doi.org/10.1016/j.apsusc.2019.06.040 .
LIU Z , ZHOU Q L , ZHAO B , et al . Few-layer N-doped porous carbon nanosheets derived from corn stalks as a bifunctional electrocatalyst for overall water splitting [J]. Fuel , 2020 , 280 : 118567 . DOI: 10.1016/j.fuel.2020.118567 http://dx.doi.org/10.1016/j.fuel.2020.118567 .
WANG J , XU F , JIN H Y , et al . Non-noble metal-based carbon composites in hydrogen evolution reaction: Fundamentals to applications [J]. Advanced Materials , 2017 , 29 ( 14 ): 1605838 . DOI: 10.1002/adma.201605838 http://dx.doi.org/10.1002/adma.201605838 .
ZHANG G , WANG P , LU W T , et al . Co nanoparticles/Co, N, S tri-doped graphene templated from in situ -formed Co, S Co-doped g-C 3 N 4 as an active bifunctional electrocatalyst for overall water splitting [J]. ACS Applied Materials & Interfaces , 2017 , 9 ( 34 ): 28566 - 28576 . DOI: 10.1021/acsami.7b08138 http://dx.doi.org/10.1021/acsami.7b08138 .
AN K L , XU X X , LIU X X . Mo 2 C-based electrocatalyst with biomass-derived sulfur and nitrogen co-doped carbon as a matrix for hydrogen evolution and organic pollutant removal [J]. ACS Sustainable Chemistry & Engineering , 2018 , 6 ( 1 ): 1446 - 1455 . DOI: 10.1021/acssuschemeng.7b03882 http://dx.doi.org/10.1021/acssuschemeng.7b03882 .
LIU J M , ZHAO S R , WANG C B , et al . Catkin-derived mesoporous carbon-supported molybdenum disulfide and nickel hydroxyl oxide hybrid as a bifunctional electrocatalyst for driving overall water splitting [J]. Journal of Colloid and Interface Science , 2022 , 608 : 1627 - 1637 . DOI: 10.1016/j.jcis.2021.10.069 http://dx.doi.org/10.1016/j.jcis.2021.10.069 .
0
浏览量
1195
下载量
2
CSCD
关联资源
相关文章
相关作者
相关机构
京公网安备11010802024621